(Bis(trifluoroacetoxy)iodo)benzene: Difference between revisions
Jump to navigation
Jump to search
m Protected "(Bis(trifluoroacetoxy)iodo)benzene": Protecting pages from unwanted edits ([edit=sysop] (indefinite) [move=sysop] (indefinite)) |
m Robot: Automated text replacement (-{{WikiDoc Cardiology Network Infobox}} +, -<references /> +{{reflist|2}}, -{{reflist}} +{{reflist|2}}) |
||
| Line 5: | Line 5: | ||
== References == | == References == | ||
{{reflist|2}} | |||
[[Category:Periodinanes|Bis(trifluoroacetoxy)iodo)benzene]] | [[Category:Periodinanes|Bis(trifluoroacetoxy)iodo)benzene]] | ||
Latest revision as of 13:46, 4 September 2012
iodo)benzene.png){kind=link}
iodo)benzene-3D-balls.png){kind=link}
(Bis(trifluoroacetoxy)iodo)benzene, C10H5F6IO4, is a hypervalent iodine compound used as a reagent in organic chemistry. The reagent is used in an acidic modification of the Hofmann rearrangement. One example is the conversion of cyclobutanecarboxamine to cyclobutylamine hydrochloride[1]. It also brings around the conversion of a hydrazone to a diazo compound, for example in the diazo-thioketone coupling. It also converts thioacetals to their parent carbonyl compounds.
References
- ↑ Almond, M. R.; Stimmel, J. B.; Thompson, E. A.; Loudon, G. M. (1988). "Hofmann Rearrangement Under Mildly Acidic Conditions Using [I,I-Bis(Trifluoroacetoxy)]Iodobenzene:Cyclobutylamine Hydrochloride from Cyclobutanecarboxamide". Organic Syntheses. 66: 132. (also in Collective Volume 8, 1993)